Vapour/air mixtures are explosive. stream been tested at a concentration of greater than 95% unless otherwise : AC414340000, AC414340025; AC414340050, AC414345000; CAS-No 107-31-3 Synonyms Formic acid methyl ester; Methyl methanoate Recommended Use Laboratory chemicals. Water soluble. Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. evaluation under their specific end-use conditions, at their own discretion Anyone intending to use this information should first verify (the time at which the permeation rate is equal to 0.1 µg/cm2/min) Please contact DuPont for specific data. Prolonged inhalation can produce narcosis and central nervous symptoms, including some temporary visual disturbance. Serged and bound seams are degraded by some hazardous liquid Flammable hydrogen is generated by mixing with alkali metals and hydrides. Flash point -27°F. including, without limitation, no warranties of merchantability or fitness Site Use Terms from the permeation behavior of the individual chemicals. (method A and B) or ASTM D6978 test methods. (USCG, 1999), Inhalation causes irritation of mucous membranes. * Breathing Methyl Formate can irritate the nose and throat. The information set forth herein reflects laboratory Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? It is intended for informational use by persons having technical skill for It is subject to revision as Heat is also generated with caustic solutions. All Rights Reserved. Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc. Closed system, ventilation, explosion-proof electrical equipment and lighting. * Methyl Formate can irritate the eyes with possible eye damage. Ingestion causes irritation of mouth and stomach and central nervous system depression, including visual disturbances. Methyl formate-d Revision Date 19-Jan-2018 Reactive Hazard None known, based on information available Stability Stable under normal conditions. including trade names and synonyms. Use the product Attributes below to configure the comparison table. METHYL FORMATE reacts with acids to liberate heat along with alcohols and acids. under or a recommendation to infringe any patent or technical information All liquid chemicals have been tested between approximately 20°C and temperature. Incompatible products. determine the level of toxicity and the proper personal protective (Select up to %1% total). Web site owner: Questions? If fabric Contact with liquid irritates eyes and may irritate skin if allowed to remain. ��A���{�;?j�>���~݇9�w�^Z���{w�3�����̌w����;�?EW���;�D�����z��n5���˶8/�Y[T˯;�!��pWD'r�,$u'O���^ sL�w�4D��vÛ��_[@w��~���.�Ă������D�����mG1��5��j�������G6��="������TC'�c�q������j�_�z�`��N;�tF� /6Q�k\oh�mf������7zn�sߖ?��9� !u�~cS��у�y�K���,v��=d+����ۤ�̛j�`;}v u��� ��nm;���=梓D�$��W;,���m��Ǜ m��Ο����kX�!sMs�����Cbt�gs�;4�!�:���i�x�ՎQ�y�gq���7 �ć����׶��Y�߻�_ˬL�[ճ�;�!/aw�ӽ��i����e|v��լYLQ����f2�Ն\����{{��"B��. Normally stable, even under fire conditions. attached gloves, visors, etc. %PDF-1.4 Less dense than water Vapors heavier than air. Safety. Storage /Producer(Sub Systems, Inc.)/CreationDate(D:20200301184236+05'00')/ModDate(D:20200301184236+05'00')/Creator(Sub Systems, Inc.) Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. these chemicals are present. endobj Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% Contact stated. Risk of fire and explosion on contact with strong oxidants. ... in connection with this information. additional knowledge and experience are gained. for a particular use and assume no liability in connection with any use of rates than the fabric. reported in minutes. Since conditions of use Methyl formate; (Formic acid, methyl ester) (107-31-3), Methyl formate; [Formic acid Methyl ester]. Methyl ester of formic acid, Methyl methanoate Colorless liquid with a pleasant odor. | Privacy. that the garment selected is suitable for the intended use. Reacts slowly with water to give formic acid, a corrosive material, and methanol, a flammable liquid. DuPont believes to be reliable. Unless otherwise stated, permeation was measured for single chemicals. Incompatible Materials Alkaline, Acids, Bases, Butyl rubber METHYL FORMATE reacts with acids to liberate heat along with alcohols and acids. (USCG, 1999). It is the user's responsibility to are damaged, end user should discontinue use Belongs to the Following Reactive Group(s). This section provides a listing of alternate names for this chemical, All chemicals have relative humidity per military standard MIL-STD-282. Exposure to moisture. and risk. Hygroscopic. becomes torn, abraded or punctured, or if seams or closures fail, or if Methyl formate, spectrophotometric grade, 99%. Please remove at least one to add a new selection. Heating will cause rise in pressure with risk of bursting. of DuPont or others covering any material or its use. are outside our control, we make no warranties, express or implied, Type in Product Names, Product Numbers, or CAS Numbers to see suggestions. Sigma-Aldrich offers a number of Methyl formate products. View information & documentation regarding Methyl formate, including CAS, MSDS & more. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 >> '������t ���0���)3�I�����'>���yoc���PD��%�������t@ɷ_�|� q��> ��^V��E�A����p��&�� u�N���T�i��h�}�k�=��ˎ=��`fa�N���n�������2�3�� ^��ZC�ài��?��| �:�&���a�����u7"��ؼl�6�Q� �w��ΟPC���i��6���B�;NχQ*"������K���̟!Ko��o�\�%TN���=TP�PRB��cL��p��3n��|�Q�v��}�����N�a�ηa��� !��u)c���Ox�=���16�` !%:MC��0�|�d� ��-8�a@�۰�F���#�g��M;�#��=��(��"�y�;3�:��b8C�~�j�Ӈ �T��}�������ڨ�:&�|g��B7/nd�Jl������X�qF�xh�s1���}n�]���N:�=j��d#���]��5$b��{�9N���*([���e�����ۃ��w����iOG��_��c27���u���7��Η��L��l�F��YN�} ����dbH6�}��p�� �H�A�����B���‡�,���{�ɾz�a����>����ÿ$[7�;!�Ο�����l|��g��|i4�f��dtb�/�O3���!����C�!�ם��#�x�v���U�a�����g�+>Q0��O��{���!������/5�x������^��C�� �F��0j'�>�g8�j��#����`'Dو��o�0��h���K��sog�����^��j���~��v���n��/ ��}m�1�������̽���L�衃݃= >���o^��|��-a;x��c,�}���� +���P�#�v�pI�����tx��J���GaU>��� �r��e�W7�yp�jn��: A clear colorless liquid with an agreeable odor. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. 4 0 obj Skin: Wear appropriate personal protective clothing to prevent skin contact. Burns readily. You have selected the maximum number of product attributes (%1%) to compare. Sorry we cannot compare more than 4 products at a time. ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Extremely flammable. 27°C unless otherwise stated. Uses advised against Food, drug, pesticide or biocidal … <> CAUTION: This information is based upon technical data that SAFETY DATA SHEET Creation Date 16-Jan-2009 Revision Date 25-Apr-2019 Revision Number 6 1. In many cases, Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur Identification Product Name Methyl formate Cat No. Reproduction of any materials from the site is strictly forbidden without permission. << Heat is also generated with caustic solutions. NO open flames, NO sparks and NO smoking. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. CDC - NIOSH Pocket Guide to Chemical Hazards - Methyl formate National Oceanic and Atmospheric Administration. equipment needed. Normalized breakthrough times "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k��ⵋN���?��^1@�������2���?��_ͦ/+�rW�\��Aۧ!Y��??�#���D�-�v}*�=�����p�;�r{og����&������wMċ�u�v!�����v���?�Ӵ������ׅLJ�f��4�.�IR�o�~�KܻO4��v���{���x��?�����Stu�S�@Z7N�f��-΋i����L�n�)&�����e]���6}�-�o�����=��y;�.��^dm�=���ѱ��?@? The fabric permeation data was generated for DuPont by independent © 2020  Merck KGaA, Darmstadt, Germany and/or its affiliates. [Note: A gas above 89°F.] Since its boiling point is lower than the human body temperature, samples of methyl formate should not be kept too long in hand. Customer Service. Conditions to Avoid Excess heat. of garment to avoid potential exposure to chemical. Methyl formate vapors may irritate lungs, so it's best to work in a well ventilated area. Highly flammable. A different temperature may have significant influence on the chemicals, such as strong acids, and should not be worn when performance of fabrics, not complete garments, under controlled conditions. Office of Response and Restoration, this information. breakthrough time; permeation rates typically increase with The permeation characteristics of mixtures can deviate considerably seams and closures have shorter breakthrough times and higher permeation Can cause temporary incapacitation or residual injury. National Ocean Service, Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Both products are dissolved in the water. EYES: First check the victim for contact lenses and remove if present. Rapidly or completely vaporizes at atmospheric pressure and normal ambient temperature. %���� Common Name: METHYL FORMATE CAS Number: 107-31-3 DOT Number: UN 1243 ----- HAZARD SUMMARY * Methyl Formate can affect you when breathed in and by passing through your skin. Keep away from open flames, hot surfaces and sources of ignition. Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration.